Product ID:EPON RESIN 1031, 43490
MSDS Date:09/09/1992
FSC:8030
NIIN:00N064980
MSDS Number: CBCNN

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Preparer: J C WILLETT

Cage: SHELO

SHELL OIL CO

4320 HOUSTON, TX 77210-5000 US

Telephone: 713-473-9461/713-241-2252

Cage: SHELO

TETRAPHENYLOLETHANE/ECH RESIN

CAS: 7328-97-4

Fraction By Weight: 99.45%

OSHA PEL N/K

ACGIH TLV: N/K

PROPANE, 1,2-EPOXY-3-PHENOXY-; (PHENYL GLYCIDYL ETHER)

CAS: 122-60-1

RTECS: TZ3675000

Fraction By Weight: 0.55%

OSHA PEL 10 PPM

ACGIH TLV: 1 PPM; A3, S

PROPANE, 1-CHLORO-2,3-EPOXY-; (EPICHLOROHYDRIN) (SARA

CAS: 106-89-8

RTECS: TX4900000

Fraction By Weight: <0.1%

OSHA PEL 5 PPM, S

ACGIH TLV: 2 PPM, S

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BRTHG IS DFCLT. GIVE ARTF RESP IF NOT

RTECS: 9999999ZZ

IS CONSCIOUS/VERY DROWSY. OTHERWISE, GIVE NO MORE

RTECS: 9999999ZZ

(2 TBSPS) SYRUP OF IPECAC. IF IPECAC IS UNAVAIL,

RTECS: 9999999ZZ

FINGER TO BACK OF THROAT. KEEP VICTIM'S HEAD BELOW

RTECS: 9999999ZZ

SUCH AS LOSS OF GAG REFLEX, CONVULSIONS/UNCON OCCUR

RTECS: 9999999ZZ

FOLLOWING INTUBATION WITH A CUFFED ENDOTRACHEAL

RTECS: 9999999ZZ

APPROP DISP FACILITY IN COMPLIANCE W/LOC

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS SECTION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: BASED ON SIMILAR PROD
TESTING, PROD IS PRESUMED TO BE MILDLY IRRIT. DUST CAN PRODUCE MECH
IRRIT. SKIN: BASED ON SIMILAR PROD TESTING, PROD IS CONSIDERED TO
BE MIN IRRIT. INHAL: MAY PRODUCE DUST WHICH MAY CAUSE MECH IRRIT
OF NOSE, THROAT, & RESP TRACT. INGEST: BASED ON SIMILAR PROD
TESTING, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:PHENYL GLYCIDYL ETHER: IARC MONO ON
EVALUATION OF CARCIN RISK OF CHEM TO MAN, VOL 47, PG 237, 1989:
GROUP 2B. (SUP DAT)
Effects of Overexposure:HLTH HAZ: PROD IS CONSIDERED TO BE SLIGHTLY TOX
IF SWALLOWED. CHRONIC: ING 1 IN TESTING DONE ON SOLN OF THIS PROD,
IN METHYL ETHYL KETONE, IT WAS FOUND THAT PROD WAS POS IN IN-VITRO
MUTAGENICITY ESSAY S: SALMONELLA, MOUSE LYMPHOMA CELLS, & CHINESE
HAMSTER OVARY CELLS. ING 2 WAS FOUND TO BE MUTAGENIC IN
IN-VITRO(SUP DAT)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN, EYE, AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS
PRODUCT.

First Aid:EYE: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN WHILE
HOLDING EYELIDS OPEN. GET MED ATTN. SKIN: REMOVE CONTAM CLTHG/SHOES
& WIPE EXCESS FROM SKIN. FLUSH W/WATER. FOLLOW BY WASHING W/SOAP &
WATER. IF IRRIT OCCURS, GET MED ATTN. DO NOT REUSE CLTHG UNTIL
CLEANED. CONTAM LEATHER ARTICLES, INCL SHOES, CANNOT BE DECONTAM &
SHOULD BE DESTROYED. INHAL: REMOVE TO FRESH AIR & PROVIDE OXYGEN IF
(ING 4)

Extinguishing Media:USE WATER FOG, "ALCOHOL" FOAM, DRY CHEMICAL OR
CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . MATERIAL WILL NOT BURN UNLESS PREHEATED.
COOL FIRE-EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:EXPLOSIVE DUST CLOUDS MAY BE PRODUCED.

Spill Release Procedures:WEAR APPRVD RESP & APPROP PERS PROT CLTHG. MAY
BURN, ALTHOUGH NOT READILY IGNITABLE. USE CAUTIOUS JUDGMENT WHEN
CLEANING UP LGE SPILLS. SHOVEL & SWEEP UP/USE INDUS VACUUM CLEANER.
AVOID GENERATING DUS T CLOUDS. PUT INTO CONTRS FOR RECLAIMING/DISP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTRS, EVEN THOSE THAT HAVE BEEN
EMPTIED, CAN CONTAIN RESIDUES OF DUST/SOLID PARTICULATES. THESE
RESIDUES MAY CREATE BOTH HLTH & FIRE/EXPLO HAZ.
Other Precautions:STATIC ELEC MAY ACCUM & CREATE FIRE HAZ. GROUND FIXED
EQUIP. BOND & GROUND TRANSFER CONTRS & EQUIP. HANDLE I/A/W HAZ
POTENTIAL OF CURING AGENT USED. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING.

Respiratory Protection:AVOID BRTHG DUST. IF EXPOS MAY/DOES EXCEED OCCUP
EXPOS LIM USE A NIOSH/MSHA APPRVD RESP TO PVNT OVEREXP. I/A/W 29
CFR 1910.134 USE EITHER NIOSH/MSHA APPRVD ATM-SUPP RESP/NIOSH/MSHA
APPRVD AIR-PURIFYIN G RESP FOR PARTICULATES.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL DUST
CONCENTRATIONS.
Protective Gloves:CHENICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:WEAR PROTECTIVE CLOTHING. EMERGENCY EYEWASH
& DELUGE SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
SMKNG/USING TOILET FACILITIES. LAUNDER CONTAM CLTHG BEFORE REUSE.
Supplemental Safety and Health
MATLS TO AVOID: ESPECIALLY PRIMARY & SECONDARY ALIPHATIC AMINES. EFTS
OF OVEREXP: ESSAYS. ING 2 MAY CAUSE CNS DEPRESS, ATOXIA, & INCOORD
VIA INGEST. CARCIN EXPLAN: EPICHLOROHYDRIN: IARC MONO, SUPP, VO L
7, PG 202, 1987: GROUP 2A. NTP 7TH ANNUAL REPORT ON CARCINS, 1994:
ANTIC TO BE CARCIN. HUMAN: RESP CANCER.

Melt/Freeze Pt:M.P/F.P Text:>171F,>77C
Vapor Pres:<1
Vapor Density:>1
Spec Gravity:>1 (H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK LUMPS

Stability Indicator/Materials to Avoid:YES
CAN REACT VIGOROUSLY W/STRONG OXIDIZING AGENTS, STRONG LEWIS/MINERAL
ACIDS, & STRONG MINERAL & ORG BASES/ (SUP DAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, ALDEHYDES & ACIDS MAY
BE FORMED DURING COMBUST. RXN W/SOME CURING AGENTS MAY PRODUCE
CONSIDERABLE HEAT.

Waste Disposal Methods:KEEP OUT OF SURF WATERS, SEWERS, & WATERWAYS
ENTERING/LEADING TO SURF WATERS. NOTIFY AUTH IF ANY EXPOS TO GEN
PUBLIC/ENVIRON OCCURS/LIKELY TO OCCUR. REPORTABLE QTY FOR THIS PROD
IS 500000 LBS, WHICH I S BASED ON PRESENCE OF ING 3. PLACE IN (ING
10)

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particular situation.